In Dumas method for estimation of nitrogen, 0.50 g of an organic compound gave 70 mL of nitrogen collected at 300 K and 715 mm pressure. The percentage of nitrogen in the organic compound is
.
(Aqueous tension at 300 K is 15 mm).
Text Solution
Verified by Experts15
(15)
Given data:
Mass of organic compound
Volume of nitrogen gas
Temperature
Total pressure
Aqueous tension
Pressure of dry nitrogen
Convert the volume of nitrogen to STP conditions (
):
Using the combined gas law: 

At STP, 22400 mL of
weighs 28 g.
Mass of
collected 
Percentage of nitrogen 


Rounding to the nearest integer, we get 15.
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